Marantz AV30 + ATI AT1825 class-AB 200x5 amp would be awesome.
But probably more pride of ownership.
ATI amps are awesome, but unless you actually need more power than the Yamaha flagship AVR, probably won't hear any difference - unless you're also in the "all amps have a sound signature of their own" camp.
For SQ, the AV30 would have access to Audyssey and/or Dirac Live/ART. I love my Yamaha manual PEQ since I can get my in-room FR to +/-1.5dB. But for many people automatic Room Correction is better or easier for them than manual PEQ.