As TLSGuy mentioned earlier, it is likely a gain related issue that can be dealt with but I would need to know the following information first.
- Model of the Emotiva amp
- Model of the DefTech speakers, or just the sensitivity specifications.
- Your seating distance.
Without the above information, everyone would be trying to help by making their own assumption of the root cause.
Note that if the Denon's pre out worked as expected, then it would work to if you use the Marantz RCA pre out for sure but it would nice to have the information I am asking then we will know for sure what the issue is with the XLR output. Also note that if your interconnects are less than 3 meters, then RCA outputs are just as good so that is a fall back solution regardless.