I was trying to add mils of thickness to the edges of the baffles to make up for the thickness of the veneer so that the edges of the baffles sit flush with the cabinets. Epoxy builds much faster than watered down wood glue. Epoxy, regardless of how thick it is, will cure evenly throughout. Air dried paints and adhesives, will typically skin over first, and then cure/shrink for months afterwards. I needed something high build that was stable. Wood glue is not meant as a gap filler or for high build.
With epoxy, you can use many different kinds of fillers/powders to make a gap filling adhesive or a workable (like bondo) putty, that will adhere to a lot more surfaces than bondo or wood putty will. These include, wood (ultra fine sawdust) flour, wheat flour, phenolic micro (easily sandable) balloons, milled glass fibers, talcum powder, alumina, graphite etc.
I've been working with composites for years. It's the materials I have on hand. I just like epoxy better than watered down vinyl. On the backs of the cabinets I used thinned, dewaxed shellac. It would have taken quite a bit of wood glue to do those.