There are too many factors that don't come up in the original question, TLS hit on many of them and I was going to say something similar. I took the assumption you designed these yourself, but of course a 100W sub, even a whole lot of them, will only give you output. That output might not sound great though, so you will just get more of not such a good thing. If quality is what you are after, then going for good drivers, proper enclosure and an amp designed for that build is the path to better sound.
500W x2 ch vs 1000w x1 to the same sub would result in the same thing.