It sounds like there is some possible misunderstanding about the use of "Transition Frequency," here.
TLS will correct if I am wrong, but his usage of this is not about the Schroeder Frequency of the room (sometimes called transition frequency), rather it is the point where the soundwaves are not being reinforced by direct reflection from the baffle (as referred to in the article below as Baffle Step Response).
From his post above:
This is what, if I understand his usage correctly, he is calling the transition frequency.
From Elliott Sound Products:
ESP - The Audio Pages. Baffle Step Compensation. How it works, and why you may need it. Includes details of how to build your own.
sound-au.com