Hi Arrt, and Welcome to Audioholics.
The gain on the A500 has to be at zero, because you don't want to have a loud pop sound from your speakers, that's all. That's the Pro version way of many amps.
Now, with your Energy speakers, you don't really need much power at all, as they are very sensitive (94db for the C-500, 91db for the C-C100 and 90db for the C-100). Also, they are an easy load (8-ohm impedance for all).
Your Yamaha 765 is fine., like you said, "everything sounds good now".
But, if you want to add an external amp, you'll gain more power of course, and you'll be able to play your Energy's louder. BUT, you cannot play them to very loud, because with their smaller drivers, they will overload.
>>> If I was you, I would not waist my money, even if that amp is cheap.
* I'm not a big Adcom fan. And in your case, I don't think you need it either anyway.
If you can try the Behringer A500 at home for your C-500s, and see if you like it, with the precaution indicated about setting the gain at zero, when powering it up, and having the option of returning it; then, go for it, and give it a shot.
Cheers,
Bob