I'd run LC(C)R in bridged mode on the AMP10 - you'll still have plenty of channels left.
Also, for two centers, you can use the custom amp assign and route a "copy" of the center channel to pretty much any channel you want and then just use the L or R of that channel. e.g. if you don't have rear heights, you can route your center to the rear heights in the AV10 and then just use L or R output from AV10 to the AMP10. On the AV10, you can bridge (BTL) that second center channel as well and still have 10 channels left on the AMP10 for your remaining speakers. A simpler approach would be to just use an XLR Y cable - which would work just fine as well IMO.
You have four subwoofer outputs so your two subs should be in good shape. I wouldn't bother with directional bass if you have the choice in the menus.