The XPA-2 is a far more powerful and better amp than the XPA-3 and XPA-5 which are built on the same specs.
The XPA-2 has 12 Transducers and brings out more subtleties than the XPA-3 according to Emotiva. Just look at the weight of the two units.
XPA-2 = 75 pounds
XPA-3 = 57 pounds and has an extra Amp
To answer your question, in an ideal world, you should use the same Powered Amp on your center channel that you do on your mains. But that is also assuming that your center channel is the same as your mains, which I'm guessing is not the case. If this is true, than you could very well level match your center with your receivers amp and use a 2 channel amp for the mains.
The only problem in doing this though, is if you ever decide to implement a separate EQ like the Behringer or Audyssey in the future, you'll need a separate amp for each channel that you are trying to calibrate.
For the money however, the XPA-3 is a great deal. I'm debating purchasing one to power my center and rears to go with my XPA-2...