Looking through the manual, there is no indication at all that you can change the zone 2 output to variable. This may be possible, but the manual does not say that it is. If it is possible, you may need to set the speakers for zone 2 as 'powered'. It is definitely the case that the receiver can ramp volume on the speaker terminals for zone 2, but nothing indicates this will impact the RCA line output connections.
I've searched the whole manual and I really haven't run into a receiver which has a specific zone 2 output that doesn't offer variable output as an option. This may be the first.
This being a very possible reality, then you will only have volume control by adjusting the pre-outs of the NAD up and down. Make SURE you start with the volume turned down so you don't blow the speakers up.