My first instinct is to just say NO, but that would not be very helpful. You are going to have to stick with a 5 speaker setup. That is because the Yamaha and Technics both appear to be 5 channel receivers. There are no additional channels to feed to another pair of speakers. Both units do not have any pre-amp outputs, so you can not send a signal to second amp or receiver any way.
If you want to connect the PC, there are five 1/8" jacks for audio out. Most motherboards can auto-sense what is connected. If you connect headphones, it will be stereo. If you connect all 5 to a surround receiver, it will process all 5 channels but that is provided that the source material is 5 channel audio and not just stereo. The 1/8" audio out jacks on the PC connect to the Multi-CH input on the Yamaha or the DVD input on the Technics. You can use individual cables, but I have seen bundled multi-cables that have 5 1/8" plugs on one end and 5 RCA plugs on the other end. You'll need to choose one receiver or the other.