My Rotel RSP-1570 pre-amp manual says: s/n ratio (IHF A-weighted) 95 db (analog bypass) 92 db (Dolby Digital, dts) 0dBFs; input sensitivity/impedence: Line Level 200 mV/100k ohms; Pre-amp Output Level/Output Impedence: 1.0V/1k ohms; Contour (LF/HF) +- 6 dB at 50 Hz/15kHz. The amp spec says s/n 137dB; 4 ohm 25dB/2.2Vrms (high), 20dB/3.9Vms (med), 15dB/6.9Vrms (low). Is it better to let the amp or the pre-amp do the "gaining"? I guess it depends if the s/n gets worse as you turn the knob on the pre-amp???
It depends on your speaker's sensitivity, and your listening habit, that is, distance, max spl you need at your mlp.
Based on the RSP-1570 pre out spec alone, you most likely need to set the buckeyeamp's gain to high. Even then, you may not be able to get to its max rated output. "may", or may not, because we don't know what is the maximum rated output of the RSP-1570, spec says 1.0 V but that likely is not the maximum.
1 V from the Rotel will only get you about 80 W into 4 ohms or 40 W into 8 ohms. That is likely enough for real world music listening depending on things mentioned above but is not even close to the buckamp Purifi based amps rated output.