No, I'm not claiming it can't happen. I'm saying that I have seen no evidence to show that it does happen.
Yes, it can take some time for caps to form completely (hours, not days or weeks though), and it takes some time (5-30 minutes in most cases) for thermal stabilization to occur. But, as Dan points out, forming the caps will happen when the maker tests the unit and switching on your system 5 minutes before you use it will take care of the rest. I wouldn't even include the 5 minute warmup period in the concept of "break-in."
I'm also not saying that Sarius didn't hear a difference. I'm just questioning the cause of the difference that was heard.
And finally, Sarius found an amp that he likes for a very low price. That's a good thing! Don't lose sight of that.
There's a very basic, rock bottom idea here. It's all about things sounding different (or not) and how that relates to how they're designed and made.
Ok, so you hear a difference. Is it repeatable? Can other people hear it too? Can other people hear it without you suggesting it to them first?
Does it hold up under blind testing? Can we then relate what you heard to science or engineering so we can show why you heard it?
There have been a number of cases where people hear differences even though no changes were made. Just the suggestion that there was a change was enough to affect their perception. I also read about an audio show where Enid Lumley was claiming that the little plastic tripods that come in pizza boxes improved the sound of components when placed on top of them or something. People heard a difference. (Enid is evidently rather persuasive in person, although she comes across as a crackpot in print.) So I think we can say that just hearing something may not be enough...
Ok, so we finally wind up with some valid info after testing. Now, how can you or others use this info to guide your purchasing decisions? That's kind of the bottom line. How do we get the best return for our expenditure of resources?