Taken from Rane Professional Audio Reference:
biamp, biamplified, or biamplification: Term used to refer to a 2-way active crossover where the audio signal is split into two paths, and using separate power amplifier channels for each driver.
BTL (bridge-tied load) Amplifiers. An amplifier configuration where the loudspeaker load is connected between the two hot outputs of two amplifiers operating in bridged amplifier mode, i.e., anti-phase, where the output of one amplifier drives the the second amplifier out of phase, or inverted, and operates at unity gain. Thus the second amplifier (usually the second channel of a two channel design) acts as a current amplifier (with inverting voltage). This doubles the output voltage (one-half from the first amplifier and one-half from the second amplifier) and theoretically produces four times the power output (double the voltage equals double the current equals four times the power). However this virtually never happens in practice since the amplifier power supply runs out of current long before four times the power is reached. Typically, amplifiers operating in bridged amplifier mode deliver twice their single-ended output power. Semiconductor audio power amplifiers use BTL configurations as a way to maximize power output from the small voltage sources found in internet appliances and automotive applications.
Yes, the Z7 is 4ohm stable for the mains.
Yes, the Z7 will let you use it's 6th and 7th channel to bi-amp the mains.
IMO, the Z7 will have no problem driving a 4ohm center channel.
No, bi-amping is not the same as bridging.