1. Ability to physically locate amplifier close to speaker to minimize speaker lead length thereby reducing losses.
2. Less noise interaction between stereo channels yields quieter operation and lower noise floor. Stereo amplifiers utilize shared component and circuit design.
3. Vibrations of the amplifier stages themselves can interfere with other channels. Separating into monoblocks helps to eliminate this common noise source.
4. There is less crosstalk (leakage) and greater stereo separation which yields enhanced stereo and fidelity effect.
5. Monoblock isolated power supplies permit least possible electronic and mechanical interaction between channels and promotes maximum linearity and stability.
6. Seperate power supplies do not rob power from the other channel under heavy loads.
7. Greater heat dissipation of two independent chassis.
now will any of that lead to better sq, I don't know but it looks cool to have a pair of amps vs a single

... My 2.2 evo2 system uses an xpa2 and I love that amp, audioholics {I believe it was aj anyway, in their review of the xpa2} said that it had the lowest cross talk noise they ever tested and that it was just as low as any mono blocks they tested...
I don't know if any of it makes the system sound better, BUT you buy what you like, its a hobby... And if you start ignoring stuff like cross talk or a little bit better design here and there, where does it end, why not just get a boombox or listen to the speaker in your ipod? If for the same price per watt or close to it you can get mono blocks for your 2 channel rig then why not? Just like the class a/b vs d questions, for a little more money you can do it how it was meant to be done with a amp built for home audio not pro audio, so just do it... {obviously Im tlaking under 300w per channel here...