I judst did that this last weekend. Using a Radio Shack spl meter, with it set to fast sit in your listening spot and, at your normal listening volume, take measurement. Foe example, if you take a reading of 68db, then you want youir sub, by itself, to register 68db. Disactivate your speakers and adjust the sub volume to get 68db from your listening spot. Help from a friend would be handy-but not imperative. Use a test disk for best results.
Hope this helps,
Mike