Dolby Digital and DTS are encoding methods. They're primarily used as a way to encode and store multichannel surround sound, which is then decoded by the receiver.
You're listening to 2-channel sources that aren't in Dolby Digital. You should be, and no doubt are, feeding 2-channel audio to your receiver. Dolby PLII and DTS Neo 6 are processing techniques that turn 2-channel or higher audio into 5 or 6 channel audio.