That higher impedance to highs is inductance, which was really high in some of them. Also, a reasonable cause of some cables being called subjectively brighter than others.
First chance I get, I'm going to measure the impedance and inductance of my speaker wires with my Parts Express WT3. It has a resistance calibration and test lead calibration, as well as measuring inductance of the voice coil anyway, so I have to think it'll work for this. I'll report back when I get the results.