First of all, I think the best tweak you can make is scooting the couch up forward. It will help both video immersion and audio. Your head so close to that back wall will make for boomy bass most likely, and the reflection of that back wall is so quick to arrive, that you cannot distinguish it from the audio coming directly from the speakers. This makes for smearing, rather than ambience.
You can balance the two things as far as video and audio, and perhaps come up with the perfect compromise. AFTER you do that, put up the treatments. (Otherwise, the 1st reflections will be at different spots).
Examples for video, with a 42" 16:9 TV:
SMPTE recommended 30 degree viewing angle = 5.7 ft viewing distance
THX recommended 36 deg viewing angle = 4.7 ft viewing distance
I use 42 deg = 4 ft viewing distance.
Its true, when you are that close, 5.7-4 ft, just how far reclined you are into the couch might dramatically change the viewing angle.
To boot, for audio listener placement, 38% of the room length for your ears is the de facto standard. Slight variation depending on the room. Alrighty . . .
First reflection point on each sidewall, I think in this case, vertically.
First reflection point on ceiling, with it arranged left/right for two viewers, rather than front/back.
Last remaining goes directly behind on you back wall, first reflection there. However, if one side sounded heavier or imbalanced, I might use this 4th treatment on that particular wall.
That's my 2 cents, and hope this helps.
jostenmeat
edit: if you ever get another set of four, I guess I would be looking at all 4 ceiling + side/front/back walls with treatments straddling 45 deg, midway. Id also probably have gone all white in this case to keep a consistent color all around. Then again, Im used to PJs where this is a much more important consideration . . .