Denon 4600? Don't find one, assume its the 4500 or 4700? How big is your room? Where's your seating in relation to the back wall? You sure 7ch is going to "fit"?
I'd just look for an amp with rca inputs, some of the amps using xlr will expect higher voltage levels than the pre-outs may be able to provide cleanly. I'm not crazy about Emotiva myself but the BASx2 might be a reasonable way to go, altho personally if going to external amp I'd think about a significantly more powerful amp(s) for the fronts and use the avr for surrounds. Amps can cost some $ tho.