The NRC graph for THD on the LS50 peaks at 100Hz, but that's due to the nature of the way the data is presented. The THD is shown relative to the output of the speaker - and the speaker's output starts dropping around 100Hz. Relative to the speaker output, the THD is quite a bit higher at 50Hz than it is at 100Hz. However, keep in mind these measurements don't include the output of the rear port. So the bass wouldn't drop off quite as rapidly, but the THD measurement isn't including any port distortions. So it's hard to make much of the THD measurements with a rear-ported speaker (not to mention that, as I've said before, the audibility of the THD is far more complex than the measurement would lead one to believe).
Anyway, as I think I've stated, as far as I know there is no way to capture this coax issue with a single IMD measurement. That's why I'm reluctant to call it a problem of IMD. It's more like intermodulation dispersion than intermodulation distortion.
Generally IMD measurements are done on a single driver. Doing IMD on a multi-way speaker, and setting one tone well in the passband of one driver and the other tone well into the passband of a different driver should give you no IMD at all. In the case of a standard two-way tweeter over woofer, a tone of 100Hz and a tone of 4kHz would put the first tone in the woofer range and the second in the tweeter range, so there should be practically no IMD (assuming infinite slope crossovers). But a tone of 100Hz and a tone of 400Hz *would* show some IMD because both tones are played by the same driver. Likewise 4kHz and 10kHz.
I think you're chasing ghosts trying to capture this complex problem with a simple measurement.