I don't believe in passive biamping making any audible difference either but it does offer theoretical differences in terms of providing separate path for the high/lo signals. so if anyone wants to try and see if they have golden ears, there is nothing to lose if he has the wires and the time. In terms of power gain, again there could be some gain, however small that is depending on the AVR. For example, the older HK AVRs focussed on investing in larger power supply and are relatively speaking, amplifier limited (power transistors etc..). In such cases, bi-amping the front channels with the unused channels should get you a little more, may be 1dB or less, considering not all channels will be driven to full output at the same time.
Again I agree any such gain will be so negligible aside from being theoretical. I am saying this all just for technical argument sake, hope you guys won't take that as being argumentative.