You have to watch out when mixing amps that they have similar output curves. For instance, if you run the tweeters off the Pioneer and the woofers off the Emo, you may run into a situation where at low volume, the bass drowns out the highs but as you turn the volume up, one amp will gain volume faster than the other so that the highs are too harsh at high volume (or vice-versa). If you are going to bi-amp, you should try to use relatively closely matched amps so they increase volume at a matched rate, like two channels of an XPA-5 per speaker.
I appreciate that Greg's experience adding power to the Studios was positive, but IIRC on two points, 1) Greg has a very large room, and 2) Greg listens to music VERY loud when drinking Scotch Whiskey, to the point of blowing speakers, neither of which condition applies here (I hope). Coolness factor aside, I think you should research this whole thing more before jumping in.