Dolby Surround is what you can get with a stereo analog connection - some material that is encoded with Dolby Surround or ProLogic2, will play back in 5.1 channels, but the sound is not true surround, it is matrixed as MarkW mentioned - the center and surrounds ARE encoded into the stereo signal, but they are bandwidth limited and they are not discrete. Regular stereo material may or may not give you a good surround effect, as the ProLogic data is not present.
You can get true, discrete surround either via digital as mentioned OR via a DVD player that has 6ch analog output and built in decoding connected to a receiver that has a 6ch analog input.