Jammer-
Your proposed set-up looks to be an acoustical mess on paper. My recommendations would be>
a) Take a listen to the Infinity TSS750 system. My buddy Bill designed them while I was there at Harman and they are the flatest response, best sounding tiny satellite-sub combo that I've heard. Now, having said that, I have to add that none of these tiny sats are capable of going down to 80Hz to hand off to a subwoofer. This type of system will get down to 150Hz at best. That's okay, most people don't notice this 80Hz to 150Hz frequency range has been absent in millions of systems since Dolby Digital/DTS receivers came out. But placement becomes critical when we're trying to achieve a seamless soundstage.
b) I'd suggest placing your TV 180 degrees opposite of what you're proposing, into the corner between the two windows. Place your couch(s) parallel to what is now your TV wall and at least 3-4 feet away. Left and right surround should be mounted next to the windows, 5.5 to 6 feet up, on the window side furtherest from where the TV is now placed. If you've got heavy drapes on the windows that's good. Aim the left and right sats into the semi-corners created by the the 4'11"/12'7" wall on the right and 3'6"/2'10" wall on the left. The reflections from these surfaces should give you some kind of immersion effect.
c) Ask a helper to place the sub that comes with the TSS-750 behind the TV and move it around the two walls behind the TV trying to stay out from the walls a bit and as close to the center as possible. Any of these little subs, none of which have any form of equalization, are tough to place without having their location often given away, and their presense made known, during a movie. So the idea is to try to anchor the total top-to-bottom sound to the screen as much as possible by putting the sub behind the TV.
c) Lastly, get some kind of padding, 2" minimum covering at least 25% of the what is now the original 12'7" TV wall. This will attenuate the slap echoes you'll get otherwise.
Good luck. And trust your ears. If you're happy with the sound that's all that matters.