It really shouldn't matter, as long as you're using a thick enough wire. Anything below 16ga isn't advisable. Since speaker wire can attenuate your sound when you run too much of a smaller gage, then I would advise you to just use thick 12ga or 10ga cable all around. That way you don't have to worry about resistance issues, even if you have 100ft cable runs. It doesn't matter if you have different size wires to surrounds and mains, as it won't make a difference. But since using big wire won't hurt the sound, why not just by a bunch of the thick stuff and put it on every speaker?