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Oh, and you can connect 2 pairs of speakers to one volume control without any issues. No need to set the ohm rating or anything on the volume control. That is for a non-multi-zone amplifier.
SOURCE (iPod/etc.)->BUS INPUT ON AMPLIIFER
Stereo Zone 1 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
Stereo Zone 2 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
Stereo Zone 3 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
Stereo Zone 4 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
Stereo Zone 5 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
Stereo Zone 6 Output of amplifier -> VOLUME CONTROL -> 2 left speakers/2 right speakers
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If you have a multi-channel amplifier, there will be some volume control setting for each zone, but if you are coming out of the headphone jack of the iPod, you can just use the volume control of the iPod to change the volume globally.
Otherwise, it should be a pre-amplified volume control level which gets adjusted. Especially with a 12-channel amplifier like you are describing. You really can't bring multiple channels from a amp into a volume control and adjust volume that way. You want to use some sort of pre-amp to adjust volume or do it directly in the iPod.
eBay has some preamp volume controls available...
TCC TC-754 Phono Preamp w/ 3 AUX Line Level Inputs & Volume Control | eBay
They would not be in the room needing volume control, so I'm just a bit confused by the setup which is being looked for here and how the 12-channel amplifier was purchased without a proper design ahead of time.
Almost always, 12-channel amps drive one or two pairs of speakers per output, and that runs to an in-room volume control. So, you get 6 volume controls and up to about 24 speakers on it in 6 different areas.
OR - a controllable preamp is hooked up to 6 (or so) controllers in multiple rooms.