It's worth having both, but AVIA is far easier to use.
My only complaint about AVIA is the video calibration. Because it is tutorial style, they explain what you have to do and then give you two minutes to do it before moving on to the next setting. If you aren't finished, you have to hit back track and suffer thru the whole explanation again. DVE pauses after the explanation and won't move forward until you hit play. So, DVE is easier/better for video calibration, IMO. DVE also has far more patterns but they are hard to get to because they are not accessible via the main menu.
There is also a subtle difference in the way they handle the subwoofer tests. AVIA will play the LFE test tone in both the subwoofer channel and the main channels, whereas DVE does not. See the AVIA website for their explanation as to why.
In short, if you only want one, stick with AVIA. But DVE is under $20 so it can't hurt to get it too and decide which one you like to use most.