As before, MACCA350 has responded before me, and responded well. DTS is almost always only on relatively new, big budget films that were recorded with good sound. So, when you think about old films, they usually will have some sort of Dolby Digital track (very few use the PCM option) and no DTS track. So if it has Dolby Digital, it tells you nothing about the sound quality; it could be very poor, or spectacular. With DTS, it is almost always used only on big budget, multichannel soundtracks (the one exception I can think of is the Superbit edition of From Here to Eternity, which has the original mono soundtrack on Dolby Digital, and a new multichannel mix in DTS). So, DTS films will pretty much always have a well recorded soundtrack (whether you listen to the DTS or DD version on the disc). Also, I am told, DTS soundtracks are often mixed with higher levels in the surrounds, and some people like that, and will therefore select DTS as their preference.
As for why "audiophiles" tend to prefer DTS, there is the fact that movies that have both pretty much always have good soundtracks, and so people associate DTS with good sound and not Dolby Digital. Also, many foolishly imagine that a larger bitrate must mean better sound. That is foolish for reasons discussed in the link in the first reply to you, though, briefly, one uses more data that tells the decoder how to decode, so it is not audio data, and also the way the data is selected for omission matters as much or more than how much data is omitted (both DTS and Dolby Digital are "lossy" compressed formats which throw away data, like MP3s). Additionally, when switching between DTS and Dolby Digital, typically the DTS soundtrack is louder, which makes it preferred, as human hearing is not linear, so the bass and treble subjectively appear greater (by being louder, not by actually having more bass or treble, though, obviously, with any new mix, someone could artificially boost the bass and/or treble). This non-linear aspect of human hearing is why so many two channel receivers of the past have "loudness compensation" switches which boost the bass (and usually the treble) to compensate for a low volume setting. You can observe this non-linear affect for yourself; simply play some music that has a lot of bass in it, and play with the volume control. As you turn the volume down, the bass and treble appear to diminish faster than the midrange. So a slightly louder sound, even if otherwise exactly the same, will seem to have more bass and more treble, and seem "clearer" and more "detailed" (of course one can hear more details if the sound is a little louder!). Now, if you had two soundtracks that were exactly the same except for the volume, you could make them sound exactly the same by adjusting the volume control to compensate for the difference, so one would not be better for being a little louder (unless some engineer really got the levels way off what they should be, so that sound is lost into the noise floor or distorted being at too high of a level).