"Nitrogen Charged" refers to the type of gas injected into the dielectric (the insulation material). Usually the material is Polyethylene (PE) or Teflon. This is generally referred to as Foamed PE or Foamed Teflon. There isn't anything special about this, as it is very common in coaxial cables. While it doesn't ensure 75 Ohm impedance, it does lower the dielectric constant which in turn lowers the capcitance of the cable. Impedance is a combination of capacitance and other metrics.
Bottom line: is it a good thing? Yes. Should you pay a lot of money for it? No. Out of curiosity, what brand of cable were you looking at?