Redbone,
It sounds like you are seeking perfection and I know the feeling.
However, its not possible unless you pay for a professional ISF calibration. When you use AVIA or DVE for calibration, you are only using 'user level' controls. To get perfection, one must use the 'service menu' and if you don't know what you are doing, you can really screw it up! So the goal is to get it as good as you can. I have a Toshiba CRT too, so my experience with calibration may give you some hints. I'm not a video expert, but I think my results were quite satisfactory.
Like most TVs, the Toshiba default is 'torch mode'; ie contrast set to max and brightness about half way. That looks good in a bright showroom but will drastically reduce the life of the tv.
1. Change the color temperature to 'warm'. Thats close to the 6500K color temperature that is recommended.
2. Leave the brightness at its default of 50%.
3. Turn the contrast down to around 50%.
4. Now use DVE to set the brightness until you can barely see the 3rd black bar. May have to go back and forth with brightness and contrast, but ideally you want contrast far lower than its default of max.
5. After brightness and contrast look ok based on the test patterns, do the sharpness. Mine ended up slightly lower than half. Just mess with it until the lines are as sharp as possible.
6. It is impossible to get R, *, and B color filters to match perfectly without using the service menu. Changing one affects the others. Toshiba tvs seem to have 'red push' - the reds are slightly pronounced. The goal is simply to get all of the colors as close as possible. I can get blue to be about perfect but then the red and green are off. You have to go through each a few times and find the best compromise.
In the end its what looks good to you anyway. Anything you do will be better than leaving the tv in torch mode.