Depends on what you mean by "channels"
Each of the 5 (or 7) are separate, distinct channels that are created when your processor decodes the incoming digital signal. For a 7.1 unit, the processor inside must be designed to decode 7.1 channels to begin with. Yours isn't.
You can certainly put a pair of speakers on the "B" speaker terminals, or even run a separate amp and speakers off of your zone two line outs, and they will play what comes from the front right/left speakers, but they won't be a separate, distinct "channel" like the other five are.