Yes, that is a high probability.
is likely to have lower IMD,
Perhaps, but would not be an issue.
perhaps have a better frequency response,
Most are already plenty good.
and doubling the power will allow you to run at your current volume with less THD.
Most likely not, but again, the thd is already below threshold of detection.
[ The receiver is probably also unable to deliver 100W per channel all channels driven, while the amplifier will be able to.
Perhaps, but what software requires full power to all channels exactly at the same instant in time?
Just going louder may be a reason to get an external 5-channel amp, because during movies you can get all channels driven instead of running out of power.
Not aware of a soundtrack that energizes all channels at the same instant to anywhere near full demand.