Do not be stuck on the idea that sealed somehow sounds so much 'tighter' than ported. A good ported sub will be able to match the sound quality of a good sealed sub.
As for the benefits of multiple sub systems, that is only true if you have some freedom to place the additional subs where it improves the frequency response. If you only have one or two places where the additional subs can be placed, you may not get any improvement at all aside from some more output. Do not expect to just add a second sub and then be blown away at how much better everything sounds. It takes some effort into calibrating the second's sub response to gain its benefits.
Read through this article. And
here is another one worth your time, and
another one.
As for crossover setting for dual subs, just experiment with different settings when you get them, and keep which ever one sounds best to you.
As for brands, if I were you, I would sell the supercube. If you want to see the difference between sealed and ported, try one of the Hsu VTF subs or RBH I-12 subs, they support both sealed and ported configurations.
Here is a roundup of subs you might consider. I would go for any of those well before the Deftech supercubes.
As for the upgrading towers from BP10s to BP30s, don't bother. If you want to upgrade, do so in a way where the difference would be immediately noticeable. No sense in spending a lot of money for a upgrade that is only subtle.