Ah that makes much more sense now.
Yes, the reflections in that small area could create a seemingly second source, but leather would only be reflective of high frequencies. Most lows would just pass through. You could absorb on the side of the couch, but IMO a better solution would be to simply move the couch back more if you could. A small end table could break up reflections easily - anything really that isn't a flat surface will scatter sound enough to prevent that late phantom source. If you were to treat the room, bass trapping and early reflections would likely make the biggest difference, not just absorbing the side of the couch.