I recommend you read this thread that I started. While I no doubt must have made some lazy factual errors, I'm pretty confident it should give you a stronger understanding of what's ACTUALLY going on. Biwiring, btw, will not change anything measurably (or audibly, unless you believe in voodoo)
Your mistake, is simply that you don't like the sound of the KEFs in your room, for whatever reason. Nothing more, nothing less. It may be possible to tweak until you get a balance you like, or perhaps they're just not the right speakers for you. Since you've now got a true solid 100WPC amplifier, you need to find speakers you like. Turn off any built in EQ switches on the amplifier. Because they lack the necessary resolution (1/12th of an octave parametric) to do meaningful equalization, they will do more harm then good.
Start by forgetting anything you've heard before about amplifier/speaker synergy, or mating, or any of that stuff. You need to find speakers that work in the room you've got to your preference. That's where the synergy will be. It'll be a long road so be patient with your wallet and remember that every time you audition, your eyes and brain are influencing what you hear as much as your ears. Figure out what you want to hear. You'll get there.
NOW - go order a pair of these:
philharmonicaudio.com