Hi Timoteo!,
Yes, I understand what you're suggesting (Home Theater magazine had a quick article in their August 2011 issue on this very topic!), and since your A-2000 delivers 2 x 130watts (I think) into 8 Ohms across the full spectrum, that's what would then be available - at a minimum - to your two rear/surrounds.
The comments following about your B&Ws 'dipping' to 3.7 Ohms are legit I think, but since your receiver's amplifiers would be loafing driving just the two, and since those 'dips' would only occur very infrequently, I would expect no issues from that, and wouldn't worry about it (set your A-2000 to 6 Ohm loads - see manual).
The XPA-5 would then drive your bi-amped fronts, and center channels.
You'd need to make sure you setup your A-2000 to output the bi-amped signals at your pre-out jacks (but they will if you've already set it up as if bi-amping the receivers own amplifiers).
What you will have to do once its all connected (because you'll be utilizing two different amplifiers with slightly different gains) is run a test audio disc, and set the levels for equal volume output given the same signal inputs for each channel.
(But I wonder if running the receiver's own YPAO will do this for you? - Might ask Yamaha...).
But if needed, your A-2000's separate channel output levels can be adjusted for this in 0.5, or 1 db increments I believe.
Your final result will be:
Front channels (bi-amped) will receive 200w x 2 each, (400w total each), from the XPA-5.
Center at 200w, from the XPA-5.
And rear/surrounds will receive 130w each, from the A-2000.
Sounds great to me - good luck, and report back!
The Mad Norseman