those things are made for using seperate amps to power the woofers and tweeters, if you do what your saying you want to do, you will ruin your speakers.
as far as what TLS said about having to have a sub for LFE, thats not true, if you set a receiver up with no subwoofer and set all the settings right, the LFE will come through the towers as i have done this before with good results. most polk speakers need alot of power, i recently bought a pair and noticed immediatly they are power hogs and needed a 5dB increase on the volume to get the same level as with my previous speakers. but you shouldnt have any trouble driving them with a 100wpc receiver, go for a good brand like denon, onkyo, or marantz as most of them seem to be able to deliver good clean power. unless u have a hugantic room i doubt you will need more power then that, 100w is ALOT more power then you think. and as far as klipsch, im not too fond of them, they are loud but the horn loaded tweeter systems sound quite harsh and they dont seem to have very good bass response.
and i agree with TLS, most of the time people turn their speakers way up to compensate for bad sound because you ears hear flatter at a high volume, if you have good full range sound, you won't need or want a really high volume.