The A Weighting is a less flat frequency response curve as compared to the C Weighting setting of the meter. It has to do with how your ears are more sensitive to certain frequencies over others, in a small nutshell.
Typically, people tend to balance their channels at an output of 75 dB, however this number is not carved in stone and people do play with it to their taste.
If you like, find a good loudness level for your mains, a volume that you would normally listen to your system at and then calibrate the rest of the speakers to match that. Note that some people run the LFE channel a little hot.
Generally, as long as all the speakers output the same, the number can be whatever you want within reason... 70 dB, 75, 80, 85... you get the picture.
Good luck.