About 1st order slopes, it seems you have some preconceptions ... maybe based on past experience. But my experience has showed a somewhat different result. I'm not a huge 1st order proponent, but I have pretty high confidence that one would work extremely well on the Peerless poly woofer. Your assertations that you need exceptional drivers just isn't true, a perfect example is just about every product that Danny Richie at GR Research puts out ... he uses 1st order on all his woofers which are far from exceptional, with a zobel that does shaping as well. My approach with paper/poly woofers is often similar to his, cross low with a 1st order on the woofer and 3rd order on the tweeter. Or with something as smooth as the Peerless Poly cones I'd at least try a 1st order on both woofer and tweeter. But a 3rd order on that woofer is just not needed.
Well, I have no doubt this would be far better than what the OP had in mind ... but also there are hundreds of published designs around that have all the supporting measurements to go with it. And I don't mean to take a shot at you by any means, but I'd never publish or suggest a design to anybody without building it, measuring it, and listening extensively.
Honestly, with those woofers I wouldn't even bother with modeling. They're extremely easy to work with, I'd just put them in a box and put a guesstimate network on it and start measuring ... tweak, measure, tweak, measure.
And why are you so worried about having any tweeter output around the resonance? It's not like anything necessarily bad happens by doing so, but of course the only way you'd know is by first measuring said tweeter's frequency response, distortion behavior, and phase/impedance. I've done a 1st order network on a Vifa XT25 before centered at 2400hz, and even with it's huge resonance peak it performs very well. I mention that speaker specifically because it's at a friends how now replacing his Dynaudio Confidence C2's while they're being repaired, and he's shocked at how good they are in comparison to a $12K speaker. It's just a 2-way sealed bookshelf with about $300 of parts.