Hey man,
I would like to give you some ideas for your HT that I think would really improve the sound, including the boominess that you have mentioned.
First, the biggest drawback to your setup is the direction that it is facing. Acoustically speaking, it is ideal for the room to be set up so that when watching the movie you are facing in the direction of the "long way" of the room, not the direction you face when watching movies.
Second, I see that you have in wall surrounds and it would suck to have to change, but if you are interesed in getting into this hobby a bit more, then pointing the HT at that window should be something for you to consider.
You may not have to do that much re-wiring of your inwall surrounds because the location of your current right surround (as your setup is right now) would make a great location for a left surround when the HT is facing the window. Then you would put the other one on the opposite wall in the same spot.
Third, if your wide couch is a problem (when the HT faces the window) you might be able to split up the couch into 2 rows of seating. You could keep 3 seats in the front row and get a cheap riser to elevate the second row of 2 seats. It would look pretty cool, I think.
Fourth, in general it is good to keep your main speakers and center channel away from the wall. Your speakers are right up against the wall and you can't really move them much closer because of the layout of the room. Big speakers against a wall might cause boominess.
When orienting the HT toward the window you could then space the entire entertainment center (including speakers, TV stand, and TV) away from the wall by about 4' to 6' this would give your speakers some room to breathe, it would keep you close to the TV and give you tons of placement options for the sub.
Just a thought.