Let me take a crack at this (never ending
) amplifier controversey.
'Headroom' does not equal 'sound quality' except when you need it; ie loud transients can require up to 10x the power to reproduce accurately. In other words, your 100 wpc receiver may be using only a few watts the majority of time but as soon as it needs the huge increase in power it can't keep up and an external amp may be better up to the task.
Don't get lost in the watts == better sound quality nonsense. If you have a 250 wpc amp, except for those brief transients when playing at a loud level, it will never use more than a few watts. So at 'normal' listening levels it will sound no different than the receiver alone - except for those amps that are 'voiced'; ie colored to impart their own particular sound quality.
I love the notion that X speakers 'need a lot of power to sound their best'. That statement makes NO logical sense whatsoever. That is equivalent to saying these speakers absolutely suck at low listening levels. Higher power won't help you through low impedance. Low impedance requires more CURRENT but of course voltage, current, and power are related so an external amp that can supply the current can supply more power as well.
As has said been said already, at normal listening levels an external amp will not likely buy you anything. At loud levels it will be more suited to dealing with transients and is usually more suited to driving low impedance loads.
If you have a large room and/or like to listen at very loud levels an external amp could be a worthwhile purchase; otherwise it is a waste of money. My little Onkyo 502 can get so loud you can't stand it in 16x18x9 room. When pushed really hard you
can tell that it is struggling but I can't stand that level for long anyway.