<font color='#000000'>Joe;
Very briefly, just because you have an amp that is rated to 200wpc, doesn't mean you will ever reach those power levels in most listening conditions, particularly for any extended amounts of time. Thus if amp #1 is 100wpc and amp#2 is 200wpc, they will play at the same loudness when driven below amp#1's limits, assuming all things being equal other than power. However, amp#2 does have 2X the power translating to 3dB added headroom or potential to play louder without audible distortion.
Clint is correct that it is better to have a more powerful amp then less, all other things being equal, to avoid running out of dynamic range. When an amp cannot produce more power, it runs into clipping which leads to audible distortion and as Clint pointed out. It essentially sends square waves or DC power to your speaker and can damage them if exposed to this clipping for too long.</font>