Your AVR allows you to reassign two of the output amplifier rear or surround channels so they instead play the front left and right channels. Saying this in manuals gives AVR owners the false impression that they can make use of amplifier capability that they would leave unused in 5.1 surround system. It is at best, misguided, and at worst, a disservice.
In most or all AVRs and amplifiers, there is one large transformer with multiple wire windings for each individual amplifier channel. The maximum power available is limited by the size and capacity of the power supply transformer. It does not matter whether you choose to use all 7 channels, or fewer channels, such 5 or 2, there is only so much juice available. Redirecting the power out put does just that, it redirects it. It cannot create more power.
It may help to think of the power supply transformer in a receiver or amplifier as similar to a car's engine, and the output channels as similar to a car's transmission. You can choose 2-wheel drive or 4-wheel drive, but the engine and its power remains the same.
The only way you can get more power than your AVR can produce is by adding another external amplifier with its own power supply transformer. For bi-amping speakers, as everetT said, it is unlikely to make an audible difference.
As far as using your Oppo, you're making this more complicated than it should be. You can certainly try wiring things so you can listen to the DAC in your AVR or the DAC in your Oppo. My own limited experience with such things is that I can hear little if any difference. Life will be simpler if you use the HDMI connections and alter the set-up through the AVR's (edit: not the Oppo) menu.