I doubt there is a large difference in the chamfer vs radius would make a difference in the listening area (maybe off axis a little?) but not that you'd notice I'd guess.
My mains have a ~5 degree tilt in the cabinet, but I think that is more because the ribbon throws such a HUGE stage that if you aim it straight out it sort of goes beyond the listening area. So I think it is more that than any time alignment.
For the Tweeter, Dennis may have had his reasons for that config, and maybe he felt the response difference wasn't enough to matter audibly? The tweeters themselves can have different response also. When you order tweeters from GR, he sends the graphs of each driver and hand selects a pair that match very closely.
I still love my CA0W1s
You can see the angle of the Carnegies