What you're trying to do is use the same speakers for a "Zone 2" function as the surround. The AVR won't do that, in fact, none of them will. The power amp channels that can be assigned to different functions are the Surround Back channels, which can be either set for Surround Back or Zone 2 (2.0 stereo). If you're just doing 5.1 in the main system, you must use the Surround L and R speaker outputs.
To complicate matters, if you were to install a switch that connected the surround speakers to either the Surround L and R outputs or the Surround Back outputs for Zone 2, and decided to use them for Zone 2 while watching a movie with 5.1 channel sound, the surround information would have nowhere to go, yet the system will not revert to 2.1 channels either. That may be a livable compromise, but you should at least be aware of it.
Not sure what wireless speakers you plan to use, but there are no line-level surround outputs, speaker outputs only.
So, if you really want to do this, what you need is a speaker selector like this:
HDMI Cable, Home Theater Accessories, HDMI Products, Cables, Adapters, Video/Audio Switch, Networking, USB, Firewire, Printer Toner, and more!
That thing is actually overkill for what you're doing, but it would work. You set your system up for 5.1 with Surround Back outputs set for Zone 2 operation. Using the switcher you can assign the surround speakers to either surround function or zone 2. Keeping in mind, we're dealing with speaker outputs here, and some wireless speakers are expecting line-level inputs. You should determine that first.