Technically all sound that is played off of a DVD is digital regardless of output format. The HD 841 can decode Dolby Digital signals into it's 5.1 analog output, which is what I am using right now. So far as I can tell there is no DTS decoding, however.
In transferring the digital signal from the player to the receiver, you are increasing, to some degree, the odds of having some kind of error. Something that could cause a small click or minor distortion (possibly almost unnoticable) on an analog signal could have a larger effect on a digital signal. A small corruption in data can yield a good sized effect in sound. I would not expect the optical connection to be very prone to having this kind of problem, though. That is, unless the Samsung's digital output section is really sensitive to some kind of interference.