Conventional wisdom seems clear on the point of stereo versus multi-channel AV in that an AVR, no matter how good, cannot match a strong 2 channel setup for stereo listening. So this isn't about power - it's about the best stereo sound.
Conventional
audiophile wisdom is that 2 channel amps excel with music while AVR's excel with movies.
This conventional wisdom gets to be wrong! For starters, and this is a very important point, there is
zero audibility data supporting the audiophile notion that an AVR is sonically compromised handling 2 channel audio in any way.
The strongly held opinion amongst audiophiles that AVR's sound poor for music are (generally) based on casual sighted tests which are so contaminated by personal bias and other systematic errors that they are useless for reaching any impartial, sonic judgement of audio equipment.
When audiophiles are forced to rely on
just their ears, not on their eyes, prior knowledge, mismatched volumes, etc to "hear" it usually leads to some very embarrassing consequences.
Assuming the above is correct (I'm perfectly happy to be told it's not), if I want to get the best from my CM10's, should I be looking at 2 channel power amps or do I need to consider a completely different approach such as using a dedicated 2 channel amp/pre-amp with HT pass-through to the Yamaha when I want to watch movies?
HT pass-through? Have you used the "pure direct" function before? The next question is : what is wrong with the sound quality at the moment?
As others have pointed out, unless your AVR is driven into nonlinear behaviour, adding a bigger, badder amp likely will have no audible benefit. The question is : is your amp audibly distorting while listening to music?