Without knowing room size and speaker sensitivity, why not do and xpa3 instead
If it were me, I would, but they're set on the price of the UPA-500. The speaker sensitivity isn't great at 86db, but the room isn't large so the 8100 and UPA-500 should be enough power.
I'm thinking use both the 8100 and UPA-500 to bi-amp the 3 fronts, then to use the remaining 2 channels on the UPA-500 for the surrounds, and finally the 8100 to power the 6th channel in the rear.
Another option is to use only the UPA-500 to power the fronts. So, use 2 channels of the UPA-500 to power the L and R, then use the remaining channel and the 8100 to power the center, and the remaining channels powered by the 8100.