It's a good idea to decouple your speakers anyway. So you can kill two birds with one stone here by using a decoupling device as your angle block.
As suggested, the Auralex MoPads are one option. They are just dark grey foam though, so I'm not sure what you'll think of the looks.
Another suggestion that I have are the Bright Star Audio IsoNodes:
IsoNodes from Bright Star Audio
What I would suggest is that you get one 4-piece set of the small IsoNodes ($14.99), and also one 4-piece set of the large IsoNodes ($24.99). The price for both sets ends up being $40, which is pretty much the same price as the Auralex MoPads.
What you can do is put the small IsoNodes at the front of your center speaker. At the back, if all you need is a small downward angle, you can just use the Large IsoNodes. If you need a steeper downward angle, you can create two spheres by taking two of the Large IsoNodes and sticking them back-to-back.
Hope that helps!