AES/EBU is Pro version of SPDIF. Even the physical connectivity looks the same, the signal is digital.
The connection between your pre-amp and amp is analog thus you'd be using just balanced XLR cables.
Nothing to do with AES/EBU.
As for benefits, if you're already using shielded unbalanced interconnects of short length (under 10ft) switching to XLR is unlikely to provide noticeable improvements. Well you'd get few extra DB in SNR and Dynamic range, but as either way - very unlikely you'd notice any difference except placebo.